Recently i came across this awesome Windows Exploit Suggester - Next Generation (WES-NG) tool and it comes handy for performing the privilege escalation. Once you have the initial access to the machine, simply grab the system information and run with WES-NG to view all the vulnerabilities in the target machine.
WES-NG link : https://github.com/bitsadmin/wesng
1) Get the package form the above link and clone it to your machine.
#git clone https://github.com/bitsadmin/wesng
2) After cloning, update the vulnerability database.
syntax : wes.py --update
3) Now, from the target machine, run systeminfo command. Copy the output on a text file, name it as systeminfo.txt and paste it in the same WES-NG folder.
4) Run WES-NG with the systeminfo.txt file as parameter.
syntax : python wes.py systeminfo.txt